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The next chapter deals with olefin complexes, such as niobium, chromium, rhenium, rhodium, platinum, and copper. The chapters on arene, cyclopentadienyl, isocyanide, hydride, and alkyl complexes explore topics ranging from bonding and electronic structure to photoreactions, photosubstitution, redox chemistry, homolysis, and decomposition.

This text is a valuable resource for photochemists and those who are interested in organometallic photochemistry. Skip to content. Concepts of Inorganic Photochemistry. Author : Arthur W. Adamson,Paul D. Concepts of Inorganic Photochemistry Book Review:. Inorganic Photochemistry. Inorganic Photochemistry Book Review:. Concepts and Models of Inorganic Chemistry. Photochemistry and Photophysics. Photochemistry and Photophysics Book Review:. Advances in Photochemistry. Author : David H.

Volman,George S. Hammond,Douglas C. Advances in Photochemistry Book Review:. Photochemistry of Organic Compounds. Photochemistry of Organic Compounds Book Review:. Author : J. Photochemistry Book Review:. Bioinorganic Photochemistry. Bioinorganic Photochemistry Book Review:. Photochemistry and Photophysics of Coordination Compounds I. Applied Photochemistry.

Author : Rachel C. Evans,Peter Douglas,Hugh D. Applied Photochemistry Book Review:. Photochemistry of Polypyridine and Porphyrin Complexes.

Author : K. Inorganic Chemistry. Author : William W. Inorganic Chemistry Book Review:. Inorganic Reaction Mechanisms. Inorganic Reaction Mechanisms Book Review:. Physical Inorganic Chemistry. This book is comprised of 14 chapters and opens with a review of the state of the art of ab initio quantum-mechanical calculations for polyatomic molecules, with particular reference to predictions of interest to photochemists. The major areas discussed are spectral predictions, substituent effects on energy gaps, and potential energy surfaces.

The following chapters explore energy transfer and molecular mobility in polymer photochemistry; the photochemistry of polyenes and aromatic-N-ylides; cis-trans isomerization in the photochemistry of vision; and aromatic aldehyde-leuco dye photoxidation. The electrochemical boundaries for the photochemistry of spectrally sensitized silver halide emulsions are also examined, along with the photochemistry of organic chromophores incorporated into fatty acid monolayers.

This monograph will be of interest to chemists in general and photochemists in particular. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on photochemistry is dedicated to photochemical reactions of a variety of compound classes, including alkenes, dienes, and polyenes, carbonyl compounds, and aromatic compounds. Additionally, photofragmentation reactions are described in a dedicated chapter.

The last chapter gives an outlook on applications of photochemistry and natural photochemical phenomena. Both parts start with a comprehensive presentation of the general principles of the pericyclic and photochemical reactions. Author : Brian Wardle File Size : Modern Molecular Photochemistry Nicholas J.

Fundamentals of Photochemistry K. Rohatgi-Mukherjee — in Chemistry. Author : K. Rohatgi-Mukherjee File Size : Photochemistry D. Bryce-Smith — in Reference. Author : D. Bryce-Smith File Size : Inorganic Photochemistry — in Science. Prior to about , photochemistry was still widely regarded as a branch of physical chemistry which might perhaps have oc casional applications in the generation of free radicals. Strangely enough, this attitude to the subject had developed despite such early signs of promise as the photodimerization of anthracene first observed by Fritzsche in , and some strikingly original pioneering work by Ciamician and Silber in the early years of this century.

These latter workers first reported such varied photo reactions as the photoisomerization of carvenone to carvone camphor, the photodimerization of stilbene, and the photoisomerization of o-nitrobenzal dehyde to o-nitrosobenzoic acid; yet organic chemists continued for another fifty years or so to rely almost wholly on thermal rather than photochemical methods of activation in organic synthesis-truly a dark age. When my colleagues and I first began in the s to study the synthetic possibilities of photoexcitation in the chemistry of benzene and its derivatives, virtually all the prior reports had indicated that benzene was stable to ultraviolet radiation.

Yet I think it fair to say that more different types of photoreactions than thermal reactions of the benzene ring are now known. Comparable growth of knowledge has occurred in other branches of organic photochemistry, and photochemical techniques have in particular made possible or simplified the synthesis of numerous highly strained organic molecules.

In this updated and expanded edition the authors summarise those classes of reaction that best illustrate the types of photochemical behaviour commonly observed for simple organic molecules.

The different products obtained from compounds subjected to thermal and photolytic activation are explained with the aid of appropriate diagrams and mechanistic schemes. Where necessary, these are backed up by simple energy level profiles. Thus, theory and empirical data are interwoven to provide a firm basis which is aided by the generous basic references at the end of each chapter.

It is aninterdisciplinary frontier. Intense activity in organic photochemistry in the last decade has produced so vast anaccumulation of factual knowledge that chemists in general have viewed it with awe. Even those chemists engaged in the study of organic photochemistry will find the rate ofdevelopment in the field perplexing to a high degree.

This series originated to fill theneed for a critical summary of this vigorously expanding field with the purpose ofdrawing together seemingly unrelated facts, summarizing progress, and clarifyingproblems.



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